Cambios de porosidad debidos a alteración de cuarcitas y pizarras en un perfil de la Raña (Montes de Toledo, España)

  1. Molina Ballesteros, Eloy
  2. García Talegón, Jacinta
  3. Herrero Fernández, Hernando
  4. Iñigo Iñigo, A. C.
Revista:
Estudios geológicos

ISSN: 0367-0449

Año de publicación: 2013

Volumen: 69

Número: 2

Páginas: 179-191

Tipo: Artículo

DOI: 10.3989/EGEOL.41185.252 DIALNET GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: Estudios geológicos

Resumen

Rañas are alluvial fan deposits of Plio-Pleistocene age that form the piedmont platforms around the mountains in the interior of the Iberian Peninsula. They are composed of cobbles, pebbles and gravels of quartzite and some quartz, all embedded within a clayey matrix displaying striking changes in hues due to hydromorphism. Beneath these platforms, the Hercynian basement is consistently deeply weathered. In the profile of the Raña, the quartzite stones located into the clayey horizon have a weathering rind that is whitish to ochre in colour, in contrast to the dark reddish hue of those located within the leaching horizon, just below the land surface. These differences are related to changes in the physical properties (e.g., bulk density and porosity), mineralogy (presence of oxyhydroxides) and weathering processes that have taken place in the profile. Such processes have led to the corrosion and replacement of the quartz grains by the iron oxyhydroxides. The main cause is the dramatic changes in the water regime occurring in the pores at the surfaces of the quartzite stones. Due to weathering the slates outcropping beneath the Raña have undergone important release of matter (ca. 30%), together with changes in the mineral association, with a progressive reduction in the component of the unweathered slates and an increase in new minerals (smectites, kaolinite and iron oxyhydroxides) upwards.

Referencias bibliográficas

  • Abreu, M.M. (1990). Ferriginous pisolites from South of Portugal. Palaeoenvironmental quaternary relics. Sciences Géologiques Bulletin (Strasbourg), 43 (2-3): 95-102.
  • Abreu, M.M. & Robert, M. (1987). Relations maghemite- quartz. Etudes dans le milieu naturel (sols rouges du Portugal) et en conditions experimentales. In: Micromorphologie des Sols (Fedoroff, N.; Besson, L.M. & Courty, A.M., Eds.), Proceedings VII International Working Meeting on Soil Micromorphology, Paris, 1985, 165-170.
  • Alcalá del Olmo, L.; Guerra Delgado, A. & Jiménez Ballesta, R. (1993). Aplicación de diversos índices edáficos en el estudio de la evolución y alteración de los suelos desarrollados sobre la formación de la Raña. In: La Raña en España y Portugal, Monografía nº 2, Centro de Ciencias Medioambientales, C.S.I.C. Madrid, 127-138.
  • Anderson L.W. & Anderson D.S., (1981). Weathering rinds on quartzarenite clasts as a relative age indicator and the glacial chronology of Mount Timpanogos, Wasach range, Utah Arctic and Alpine Research, 13: 25-31. http://dx.doi.org/10.2307/1550623
  • Aragoneses F.J. & García González M.T., (1991). High charge smectite in Spanish "Raña" soils. Clays and Clay Minerals, 39, 2: 211-218. http://dx.doi.org/10.1346/CCMN.1991.0390213
  • Brady N.C., (1990). The nature and properties of Soils. MacMillan Publ. Co. (10th Edition), New York, 621 pp.
  • Borger H. (1997). Enviromental changes during the Tertiary: the examples of palaeoweathering residues in Central Spain. In: Palaeosurfaces: Recognition, Reconstruction and Palaeoenviromental Interpretation, In: (M. Widdowson, Eds.), Geological Society of London, special publication nº 120, 159-173. http://dx.doi.org/10.1144/GSL.SP.1997.120.01.11
  • Brinkman R., (1970). Ferrolisis: a hydromorphic soilforming process. Geoderma, 3: 199-206. http://dx.doi.org/10.1016/0016-7061(70)90019-4
  • Chaussidon J. & Pédro G., (1979). Rôle de l'état hydrique du système poreux sur l'évolution du milieu: realite de l´alteration dans les systemes a faible teneur en eau. Bulletin de l´Association francaise pour l´Etude du Sol Science du Sol (2-3), 223-237.
  • Chauvel A. & Pédro G., (1978). Sur l'importance de l'extreme dessication des sols (ultra dessication) dans l'évolution pédologique des sols tropicales à saisons contrastées. Comptes Rendus Academie des Sciences de Paris, 286: 1581-1584.
  • Chinn T.J.H., (1981). Use of rock weathering rind thickness for Holocene absolute age-dating in New Zeland. Arctic and Alpine Research, 13: 33-45. http://dx.doi.org/10.2307/1550624
  • Clausell J.V., Bastida J., de la Torre J. & Ramo P., (2001). Balance de masas en procesos de alteración sobre pizarras paleozoicas del Macizo Ibérico. Actas III Congr. Ibérico de Geoquímica y VIII Congr. Geoquímica de España, Zaragoza, 347-350.
  • Colman S.M., (1981). Rock weathering rates as function of time. Quaternary Research 12: 250-264. http://dx.doi.org/10.1016/0033-5894(81)90029-6
  • Colman S.M. & Pierce K.L., (1981). Weathering rinds on andesitic and basaltic stones as a Quaternary age indicator, Western United States. U.S. Geological Survey Professional Paper, 1210: 1-56.
  • Cuadrado S., Ingelmo F. & Hernández J., (1987). Características hidrofísicas y estudio del régimen hídrico de los suelos de las Rañas al norte del Sistema Central. Report: Dinámica de sedimentos y erosión hídrica, Almería, Spain (unpublished).
  • Espejo R., (1978). Estudio del perfil edáfico y caracterización de las superficies tipo Raña del sector Ca-amero- Horcajo de los Montes. PhD. Thesis ETS Ingenieros Agrónomos, Madrid: 477 pp.
  • Espejo R. (1987). The soils and ages of the Rañas surfaces related to the Villuercas and Altamira mountain ranges (Western Spain). Catena, 14: 399-418. http://dx.doi.org/10.1016/0341-8162(87)90012-9
  • Espejo R.; Pardo E.; Peregrina F.; Terefe T.; Gómez V., (2003). Morphological and mineralogical differences between soils in the Pliocene piedmonts related to the South and North sides of the Montes de Toledo. In: (J.L. Pérez-Rodríguez, Ed.), Applied Study of Cultural Heritage and Clays, C.S.I.C. Madrid, 415-424.
  • Etienne, S., (2002). The role of biological weathering in periglacial areas: a study of weathering-rinds in south Iceland. Geomorphology, 47: 75-86. http://dx.doi.org/10.1016/S0169-555X(02)00142-3
  • Etienne, S. & Dupond, J., (2002). Fungal weathering on basaltic rocks in cold oceanic enviroment (Iceland): comparison between experimental and fiel observations. Earth Surface Processes and Landforms, 27: 737-748. http://dx.doi.org/10.1002/esp.349
  • Gallardo, J.; Pérez González, A. & Benayas, J., (1987). Paleosuelos de los piedemontea villafranquienses y de las terrazas pleistocenas de la región del valle del Henares- Alto Jarama. Boletín Geológico y Minero, 98: 27-39.
  • Ingelmo, F.; Cuadrado, S.; Hernández, J. & Ibá-ez, A., (1991). Degradación física de los suelos de una zona de Rañas de la provincia de Salamanca. Suelo y Planta, 1: 619-630.
  • Í-igo, A.C.; García-Talegón, J.; Molina, E.; Pérez-Rodríguez, J. L.; Vargas, M. & Vicente M.A. (1994). Granites employed in Avila (Spain): II.- Petrophysical characteristics ». Materiales de Construcción, 44 (233): 28-37.
  • Jiménez Ballesta, R. & Ibá-ez Martí, J.J., (1993). Iron oxides in soils on Plio-Quaternary surfaces. In: La Raña en España y Portugal, Monografía nº 2, Centro de Ciencias Medioambientales, C.S.I.C. Madrid, 223-232.
  • Martínez Lope, M.J.; García González, M.T. & Molina Ballesteros E., (1995). Relationships between geomorphology and palaeoweathering on the hercynian basement in Central Spain. A mineralogical and geochemical approach. Revista de la Sociedad Geológica de España, 8 (1-2): 127-136.
  • Meunier, A.; Sardini, P.; Robinet, J.C. & Pret D., (2007). The petrography of weathering processes: facts and outlooks. Clay Minerals, 42: 415-435. http://dx.doi.org/10.1180/claymin.2007.042.4.01
  • Molina, E.; García, M.T. & Espejo, R., (1991). Study of palaeoweathering in the Spanish Hercynian basement. Catena, 18: 345-354. http://dx.doi.org/10.1016/0341-8162(91)90030-2
  • Molina Ballesteros, E. & Cantano Martín, M., (2002). Study of weathering processes developed on old piedmont surfaces in Western Spain: new contributions to the interpretation of the "Raña" profiles. Geomorphology, 42: 279-292. http://dx.doi.org/10.1016/S0169-555X(01)00091-5
  • Molina Ballesteros, E.; García-Talegón, J.: I-igo, A.C.; González-Sánchez, M. & Herrero-Fernandez, H., (2011). Importance of porosity and transfer of matter in the rock weathering processes. Two examples in Central Spain. Environmental Earth Sciences, 64(7): 1741-1754. http://dx.doi.org/10.1007/s12665-011-1015-y
  • Morris, R.C. & Fletcher, A.B. (1987). Increased solubility of quartz following ferrous-ferric iron reactions. Nature, 330 (10): 558-561. http://dx.doi.org/10.1038/330558a0
  • Nahon, D.B. (1991). Introduction to the petrology of soils and chemical weathering. John Wiley & Sons Inc. New York, 313 pp.
  • Oguchi, C.T. (2004). A porosity related diffusion model of weathering rind development. Catena, 58: 65-75. http://dx.doi.org/10.1016/j.catena.2003.12.002
  • Oguchi, C.T. & Matsukura, Y. (1999). Effect of porosity on the increase of weathering-ring thickness of andesite gravel. Engineering Geology, 55: 77-89. http://dx.doi.org/10.1016/S0013-7952(99)00108-8
  • Pardo, E.; Gallardo, J.; Pérez-González, A. & Gómez- Miguel V., (1993). Variabilidad morfológica de suelos en el piedemonte de la Raña de la vertiente norte de Montes de Toledo. In: La Raña en España y Portugal, Monografía nº 2, Centro de Ciencias Medioambientales, C.S.I.C. Madrid, 149-157.
  • Pédro, G. (1993). Un phénomène normal de la surface de la planete : l'alteration des roches. In: Alteración de granitos y rocas afines, (M.A. Vicente Henández, E. Molina Ballesteros & V. Rives Arnau, Eds.), C.S.I.C. Madrid, 17-50.
  • Tardy, Y. & Nahon, D. (1985). Geochemistry of laterites. Stability of Al-goethite, Al-hematite and Fe3+- kaolinite in bauxites and ferricretes. An approach to concretion formation. American Journal of Scicience, 285: 865-903. http://dx.doi.org/10.2475/ajs.285.10.865
  • Vaudour, J., (1979). La region de Madrid. Alterations, sols et paléosols. Editions OPHRYS, 390 pp.
  • Vicente, M.A.; Molina, E. & Espejo, R., (1991). Clays in paleoweathering processes: study of a typical weathering profile in the Hercynian basement in the Montes de Toledo (Spain). Clay Minerals, 26: 81-90. http://dx.doi.org/10.1180/claymin.1991.026.1.08
  • Vicente, M.A.; Elsass, F.; Molina, E. & Robert M. (1997). Paleoweathering in slates from the Iberian Hercynian Massif (Spain): investigation by TEM of clay mineral signatures. Clay Minerals, 32: 435-451. http://dx.doi.org/10.1180/claymin.1997.032.3.06
  • Vidal, M.; Martínez-Lope, M.J.; Laya, H. & Roquero, C. (1993). Estudio de la composición y génesis de las gravas y gravillas ferruginosas de los suelos de las Rañas y terrazas fluviales en relación a sus materiales originales en el N.O. de León. In: La Raña en España y Portugal, Monografía nº 2, Centro de Ciencias Medioambientales, C.S.I.C. Madrid, 103-113.
  • Walsch, J. & Dultz S. (2010). Effects of pH, Ca and SO4 concentration on surface charge and colloidal stability of goethite and hematite. Consequences for the adsortion of anionic organic sustances. Clay Minerals, 45: 1-13. http://dx.doi.org/10.1180/claymin.2010.045.1.01
  • Williams, L.A. & Crerar, D.A. (1985). Silica diagenesis, II: General mechanisms. Journal of Sedimentary Petrology, 55 (3): 312-321.