Solvent Effects on the Enthalpy and Entropy of Activation for the Hydrolysis of β-Lactones
- Calle, Emilio
- Manso, José A.
- Pérez-Prior, M. Teresa
- del Pilar García-Santos, María
- Casado, Julio
ISSN: 0095-9782, 1572-8927
Año de publicación: 2008
Volumen: 37
Número: 4
Páginas: 451-457
Tipo: Artículo
Otras publicaciones en: Journal of Solution Chemistry
Referencias bibliográficas
- García-Santos, M.P., Calle, E., Casado, J.: Amino acid nitrosation products as alkylating agents. J. Am. Chem. Soc. 123, 7506–7510 (2001)
- García-Santos, M.P., González-Mancebo, S., Hernández-Benito, J., Calle, E., Casado, J.: Reactivity of amino acids in nitrosation reactions and its relation to the alkylating potential of their products. J. Am. Chem. Soc. 124, 2177–2182 (2002)
- García-Santos, M.P., Calle, E., Casado, J.: A method for the kinetic study of amino acid nitrosation reactions. Polyhedron 22, 1059–1066 (2003)
- Lawley, P.D.: Carcinogenesis by alkylating agents. In: Searle, C.E. (ed.) Chemical Carcinogens, Chap. 7, 2nd edn. ACS Monograph, vol. 182. American Chemical Society, Washington (1984)
- Pérez-Prior, M.T., Manso, J.A., García-Santos, M.P., Calle, E., Casado, J.: Reactivity of lactones and GHB formation. J. Org. Chem. 70, 420–426 (2005)
- Manso, J.A., Pérez-Prior, M.T., García-Santos, M.P., Calle, E., Casado, J.: A kinetic approach to the alkylating potential of carcinogenic lactones. Chem. Res. Toxicol. 18, 1161–1166 (2005)
- CRC Handbook of Chemistry and Physics, 85th edn. CRC Press, Boca Raton (2004–2005)
- Van Duuren, B.L.: Carcinogenic epoxides, lactones, and halo-ethers and their mode of action. Ann. N.Y. Acad. Sci. 163, 633–651 (1969)
- Tommila, E.: The influence of the solvent on reaction velocity XII. The solvolysis of alkyl benzenesulphonates in acetone-water and dioxane-water mixtures. Acta Chem. Scand. 9, 975–988 (1951)
- Leffler, E., Grunwald, E.: Rates and Equilibria of Organic Reactions as Treated by Statistical, Thermodynamic, and Extrathermodynamic Methods. Dover, New York (1963), pp. 397–402
- Winstein, S., Fainberg, A.H.: Correlation of solvolysis rates. IV. Solvent effects on enthalpy and entropy of activation for solvolysis of t-butyl chloride. J. Am. Chem. Soc. 79, 5937–5950 (1957)
- Tommila, E., Jutila, J.: Hydrolysis and alcoholysis of sulphonic esters. Acta Chem. Scand. 6, 844–853 (1952)
- Tommila, E., Merikallio, E.: Effect of the solvent on reaction velocity. (VI) Hydrolysis of alkyl esters of benzenesulfonic acid in dioxane-water mixtures. Suom. Kemistil. 26B, 79–80 (1953)
- Tommila, E., Tiilikainen, M., Voipio, A.: Effect of the solvent on reaction velocity. (X) Solvolysis of alkyl halides in acetone-water mixtures. Ann. Acad. Sci. Fenn. 65, 1–26 (1955)