Reactividad de S-metiluros ditiooxalatos de alquilo frente a dipolarófilos

  1. I. Tapia 1
  2. V. Alcazar 1
  3. Volker Weinrich 1
  4. J. R. Morán 1
  5. J. Valls 1
  1. 1 Departamento de Química Orgánica, F. de C. Químicas, Universidad de Salamanca
Journal:
Anales de Química

ISSN: 1130-2283

Year of publication: 1990

Volume: 86

Issue: 6

Pages: 669-674

Type: Article

More publications in: Anales de Química

Abstract

Alkyl dithiooxalates S-methylides have been generated by reacting the thiocarbonyl compound and diazomethane. The reactivity of these ylides towards dipolarophiles and the stereochemistry of the cycloaddition has been studied