Synthesis and Structure of the Diterpenoid Peucelinendiol
- Grande, Manuel 1
- Moran, Joaquín R. 1
- Alcázar, Victoria 1
- 1 Department of Organic Chemistry, F. C. Químicas, University of Salamanca
ISSN: 0009-2673, 1348-0634
Datum der Publikation: 1988
Ausgabe: 61
Nummer: 12
Seiten: 4435-4437
Art: Artikel
Andere Publikationen in: Bulletin of the Chemical Society of Japan
Zusammenfassung
The synthesis of peucelinendiol has been carried out starting from geraniol, and using as a key intermediates the anion of phenylthiogeraniol and (−)-geraniol epoxide obtained by the Sharpless procedure. Its structure was stablished as (6S,7R)-7-hydroxymethyl-2,6,10,14-tetramethylpentadeca-2,9,13-trien-6-ol. Isopeucelinendiol, epipeucelinendiol, and epiisopeucelinendiol were also synthesized