Synthesis and Structure of the Diterpenoid Peucelinendiol
- Grande, Manuel 1
-
Moran, Joaquín R.
1
- Alcázar, Victoria 1
- 1 Department of Organic Chemistry, F. C. Químicas, University of Salamanca
ISSN: 0009-2673, 1348-0634
Année de publication: 1988
Volumen: 61
Número: 12
Pages: 4435-4437
Type: Article
D'autres publications dans: Bulletin of the Chemical Society of Japan
Résumé
The synthesis of peucelinendiol has been carried out starting from geraniol, and using as a key intermediates the anion of phenylthiogeraniol and (−)-geraniol epoxide obtained by the Sharpless procedure. Its structure was stablished as (6S,7R)-7-hydroxymethyl-2,6,10,14-tetramethylpentadeca-2,9,13-trien-6-ol. Isopeucelinendiol, epipeucelinendiol, and epiisopeucelinendiol were also synthesized